Found 10006 publications. Showing page 186 of 401:
2008
Low concentrations of persistent organic pollutants (POPs) in air at Cape Verde
Ambient air is a core medium for monitoring of persistent organic pollutants (POPs) under the Stockholm Convention
and is used in studies of global transports of POPs and their atmospheric sources and source regions. Still,
data based on active air sampling remain scarce in many regions. The primary objectives of this study were to
(i) monitor concentrations of selected POPs in air outside West Africa, and (ii) to evaluate potential atmospheric
processes and source regions affecting measured concentrations. For this purpose, an active high-volume air
sampler was installed on the Cape Verde Atmospheric Observatory at Cape Verde outside the coast of West
Africa. Sampling commenced in May 2012 and 43 samples (24 h sampling) were collected until June 2013. The samples were analyzed for selected polychlorinated biphenyls (PCBs), polybrominated diphenyl ethers (PBDEs), hexachlorobenzene (HCB) and chlordanes. The concentrations of these POPs at Cape Verde were generally low and comparable to remote sites in the Arctic for several compounds. Seasonal trends varied between compounds and concentrations exhibited strong temperature dependence for chlordanes. Our results indicate
net volatilization fromthe Atlantic Ocean north of Cape Verde as sources of these POPs. Air mass back trajectories
demonstrated that air masses measured at Cape Verdewere generally transported fromthe Atlantic Ocean or the North African continent. Overall, the low concentrations in air at Cape Verde were likely explained by absence of major emissions in areas from which the air masses originated combined with depletion during long-range atmospheric
transport due to enhanced degradation under tropical conditions (high temperatures and concentrations of hydroxyl radicals).
2018
Background: Positive associations have been reported between persistent organic pollutants (POPs) and type 2 diabetes mellitus (T2DM); however, causality has not been established. Over the last decades, environmental exposure to legacy POPs has decreased, complicating epidemiological studies. In addition, physiological risk factors for T2DM may also influence POP concentrations, contributing to a complex network of factors that could impact associations with T2DM. Longitudinal studies on this topic are lacking, and few have assessed prospective and cross-sectional associations between repeated POP measurements and T2DM in the same individuals, which may shed light on causality.<p> <p>Objectives: To compare longitudinal trends in concentrations of polychlorinated biphenyls (PCBs) and organochlorine pesticides (OCPs) in T2DM cases and controls, and to examine prospective and cross-sectional associations between PCBs, OCPs and T2DM at different time-points before and after T2DM diagnosis in cases. <p>Methods: We conducted a longitudinal, nested case-control study (1986–2016) of 116 T2DM cases and 139 controls from the Tromsø Study. All participants had three blood samples collected before T2DM diagnosis in cases, and up to two samples thereafter. We used linear mixed-effect models to assess temporal changes of POPs within and between T2DM cases and controls, and logistic regression models to investigate the associations between different POPs and T2DM at different time-points. <p>Results: PCBs, trans-nonachlor, cis-nonachlor, oxychlordane, cis-heptachlor epoxide, p,p’-DDE, and p,p’-DDT declined more slowly in cases than controls, whereas β-HCH and HCB declined similarly in both groups. Most POPs showed positive associations between both pre- and post-diagnostic concentrations and T2DM, though effect estimates were imprecise. These associations were most consistent for cis-heptachlor epoxide. <p>Discussion: The observed positive associations between certain POPs and T2DM may be because of higher POP concentrations within prospective T2DM cases, due to slower temporal declines as compared to controls.
2022
2006
2004
Long-term trends of short-lived pollutants in the Arctic, their source regions and emissions. NILU F
2010
2014
2010
Long-term trends of air pollutants at national level 2005-2019
Trend calculations of air pollutants for the periods 2005-2019 have been applied. Sulphur dioxide shows the largest decrease of all pollutants with a reduction of the order of 60-70 %. The agreement between reported emission data and measured concentrations are quite good. For NO2, a mismatch between the trend in air concentrations and NOx emissions is found. While the overall NOx emissions are reported to be reduced by 45 %, the measured NO2 data indicate a decline of the order of 30 % although marked differences between the countries are found. This mismatch could not be explained by changes in meteorology as this is accounted for. Possible reasons for the mismatch could be the NO2/NOx ratio of the emissions, changes in baseline hemispheric ozone concentration and natural emissions. For PM data (PM10 and PM2.5) we find an opposite mismatch, meaning that the PM concentrations show stronger downward trends than the reported emissions. This is likely an effect of the importance of secondary aerosols which are mitigated by other activities than the direct PM emissions. An overall reduction in PM10 of the order of 30-38 % is found during 2005-2019 while the direct emissions give a reduction that is 5-10 percentage units smaller. Similar results are found for PM2.5, but these findings are uncertain due to the less amount of long-term data. For O3, our findings are in line with earlier studies noting that the annual mean ozone concentration has increased while the high peaks have been reduced. But the reduction of the peaks is now within only a few percent and non-significant, while for the 2000-2017 period it was significant and about 10%.
ETC/ATNI
2021
2008
2014
The UK Toxic Organic Micro Pollutants (TOMPs) Network, which has operated since 1991, collects ambient air samples at six urban, rural, and semi-rural sites across England and Scotland, using high-volume active air samplers [1]. Furthermore, in 1994, a latitudinal sampling transect from the south of England to the north of Norway was established with eleven sampling sites, mainly in remote locations, using Semi-Permeable Membrane Devices (SPMDs) as passive air samplers [2]. Both networks provide continuous, long-term ambient air trend data for a range of Persistent Organic Pollutants (POPs), including PCBs and PBDEs, and have helped demonstrating a decline in POPs air concentrations over the last three decades. However, in recent years no further significant declines have been observed. SumPCB and SumPBDE levels in the UK are lowest at the rural sites and highest for the urban sites (TOMPs), and they generally decrease from the south of England to the north of Norway (UK/Norway) in line with expectations. Higher values at less remote sites and sites downwind from population centres show that POPs concentrations may still mainly be influenced by primary emissions. Concentrations at semi-rural sites lie between rural and urban sites; however, they can exceed the latter in some years. This can probably be attributed to short-term local effects. The data from the TOMPs network shows that concentrations of PCBs are higher in warmer than in colder months, while the seasonal patterns are less uniform for PBDEs.
2018
2017
2022
2016
Aerosols are an important constituent of the atmosphere both influencing the climate system and contributing to increasing pollution of the Arctic. At the same time, their adequate monitoring is a big challenge, as instruments on the ground only can sample aerosols in the lowermost atmosphere. For this reason, these measurements are complemented with observations of aerosol optical depth (AOD) which quantify the total amount of aerosols throughout the atmosphere from the attenuation of direct sunlight (and moonlight). This procedure requires extremely careful instrument calibration and removal of cloud contaminated data. In Svalbard, such measurements have been performed by several research groups with different instruments, mostly in Ny-Ålesund and in Hornsund, but also on research vessels offshore. In the framework of the SSF Strategic Grant project ReHearsol, all AOD data from the Svalbard region since 2002 have been collected and made available to the SIOS research community. They indicate that number and intensity of Arctic haze episodes occurring in late winter and spring have decreased consistently and significantly in the last 20 years, while pollution events in summer/early autumn, caused by boreal biomass burning, are on the rise, though not as consistently. Comparison between in-situ measurements at Gruvebadet Atmosphere Laboratory in Ny-Ålesund and AOD measurements indicate that most (more than 65%) of the episodes with high aerosol load are not captured by surface measurements. This finding does not change when one includes in-situ measurements at Zeppelin Observatory (475 m a.s.l.). Studying extensive high-AOD episodes such as those in summer 2019 requires a multi-tool approach including in-situ and remote-sensing measurements combined with model tools.
2023
2021
2004