Found 10488 publications. Showing page 407 of 420:
Anthropogenic particles in surface waters from Adventfjorden (Svalbard)
The ubiquitous presence of microplastics and other anthropogenic compounds in the marine environment are unfortunately not surprising anymore. Recent publications are revealing the occurrence of those synthesized particles in even remote and/or pristine areas in different marine matrices like biota, water and sediment. Nevertheless, the knowledge about sources and transport mechanisms of those anthropogenic particles (APs) is still lacking, especially in the Arctic. In this study we investigated surface waters from Isfjorden and the branching Adventfjorden, where Longyearbyen the largest settlement of Svalbard is located. Here, untreated wastewater is released into the fjord system. At two sample sites upstream and two sample sites downstream, three replicates at each location have been collected in June 2021. APs larger than <50μm were investigated regarding size, shape, and polymer type via μFTIR spectroscopy. At each sampling station, APs were present. The highest concentration of APs was found upstream and downstream Isfjorden; whereas lower concentrations were found within Adventfjorden, closest to the wastewater outlet. Additives and polypropylene showed the highest frequencies. Besides local sources like the untreated wastewater, freshwater inputs, ship traffic or the northwards long-range transport from the south into the Arctic needs to be considered.
2025
This study examines how southern wintering areas may contribute to organochlorine (OCs) loads in arctic seabirds during breeding. Light-sensitive geolocators (GLS loggers) were deployed on Arctic skuas (Stercorarius parasiticus) in one high arctic and two subarctic colonies. Hexcahlorobenzene (HCB), chlordanes, mirex, p,p′-dichlorodiphenyldichloro-ethylene (p,p′-DDE), and polychlorinated biphenyls (PCBs) were measured in the blood of breeding adults at the nest (58 individuals, a total of 128 samples) in northern Norway and Svalbard between 2009 and 2015. We compared OC concentrations and OC profiles among nesting skuas wintering in five Atlantic regions, determined by the GLS loggers: the coast of Argentina, the Caribbean, off West Africa, off the coast of southern Africa, and the Mediterranean Sea. As predicted, HCB, which is semi-volatile and has high long-range transport potential, showed high prevalence in birds wintering in all regions except the Mediterranean. Mirex showed the highest prevalence in birds wintering off the coasts of Argentina and southern Africa, in accordance with high background levels previously documented in the Southern Ocean. Chlordanes were particularly prevalent in skuas wintering off southern Africa, whereas p,p′-DDE seemed relatively evenly distributed among wintering areas. As predicted, the prevalence of PCBs was much higher in birds wintering in the Mediterranean Sea than in birds from other regions. This study thus suggests that the Mediterranean Sea and the mid- and southern Atlantic are essential sources of different OCs in the blood of Arctic skuas breeding in the European Arctic.
2025
This study critically examines the workflow for untargeted analysis of volatile organic compounds (VOCs) in ambient air, from sampling strategies to data interpretation by using GC-HRMS. While untargeted approaches are well-established in liquid chromatography (LC) due to advanced-deconvolution tools and extensive metabolomic libraries, their application in gas chromatography (GC) remains less developed, particularly for VOCs. The high structural isomerism of VOCs and the relative novelty of GC-based untargeted methodologies present unique challenges, including limited software tools and reference libraries. Air samples from suburban and rural sites in central Italy were analyzed to explore chemical diversity and address methodological gaps. This study evaluates critical decisions, such as sampling strategies, extraction techniques, and data-processing workflows, highlighting the limitations of automated deconvolution tools and the need for manual validation. Results revealed distinct source contributions, with suburban areas showing higher levels of anthropogenic compounds and rural areas dominated by biogenic emissions. This work underscores the potential of GC-HRMS untargeted analysis to advance environmental chemistry, while addressing key pitfalls and providing practical recommendations for reliable application. By bridging methodological gaps, it offers a roadmap for future studies aiming to integrate untargeted and targeted approaches in air quality research.
2025
This document provides technical details and support for the implementation of air quality monitoring under the Directive (EU) 2024/2881 of the European Parliament and of the Council of 23 October 2024 on ambient air quality and cleaner air for Europe (recast) (AAQD, Directive (EU) 2024/2881). It presents an overview of current knowledge and best practices, signposting to existing technical guidance on air quality monitoring and to sources of ongoing technical guidance development. This document does not formulate any legal provisions and as such, it does not have a legally binding value.
Publications Office of the European Union/European Commission. Directorate-General for Environment
2025
2025
2025
Tire particles can enter the marine environment e.g. through direct discharge of road runoff, sewage systems or riverine inputs. Their fate in marine waters remains largely unknown, though the deep sea could be a final sink as for other marine litter. To simulate these conditions, we investigated in laboratory-controlled conditions the effects of high-hydrostatic pressure [20 MPa] vs atmospheric pressure [0.1 MPa] on the leaching of 17 organic compounds from cryo-milled tire tread particles (μm sized) and crumb rubber particles (mm sized) into natural seawater. We monitored the abundance of heterotrophic prokaryotes in the leachates over the 14 day exposure period under biotic conditions. Abiotic controls were employed to delineate the influence of prokaryotes on the fate of leached chemicals. Our results showed leaching of dissolved organic carbon and target chemicals under all experimental conditions, with higher concentrations of certain target chemicals under high-hydrostatic pressure conditions (e.g., 1,3-diphenylguanidine [DPG]: max. 703 (20 MPa) vs 119 μg/L (0.1 MPa) from cryo-milled tire tread particles under biotic conditions). Under abiotic conditions leaching was weaker for DPG and other chemicals, with contrasting trends for chemicals prone to biotransformation. In crumb rubber leachates chemical concentrations increased with time, but showed no significant differences between biotic/abiotic or high-hydrostatic/atmospheric pressure conditions. Prokaryotic abundance increased in all samples containing tire particles compared to seawater controls, indicating the use of the rubber and/or leached chemicals as an energy source.
2025
NO2-måling i omgivelsene til Eramet Sauda
På oppdrag fra Eramet Sauda AS har NILU utført målinger av NO2 i omgivelsene til smelteverket i Sauda. Målingene ble utført med NOx-monitor ved Birkelandsvegen nordøst for bedriften. I tillegg ble NO2 målt med passive prøvetakere ved 3 steder i Sauda. Måleperioden varte fra 30. august 2024 til 10. mars 2025. Norske grenseverdier for luftkvalitet (NO2) og luftkvalitetskriterier ble overholdt ved Birkelandsvegen for alle midlingsperioder. Formålet med prosjektet var å vurdere effekten av det nye energigjenvinningsanlegget (bestående av 7 gassmotorer) på NO2 konsentrasjonen. Det ble ikke funnet noen sammenheng mellom vindretning fra sør-sørvest (fra bedriften mot målestasjonen), motordrift og NO2 konsentrasjonene målt ved måleboden.
NILU
2025
Kartlegging av utslipp fra aktiviteter i Oslo Havn
Stiftelsen NILU har utarbeidet en utslippsberegning for aktiviteter på land ved Oslo Havn. Arbeidet omfatter innhenting av aktivitetsdata og utslippsfaktorer fra relevante kilder. Utslippet er beregnet for Dagens situasjon 2023 og framskrevet til 2030 og 2040. For 2040 er det også regnet på effekten av å bytte til bio-basert brensel i fabrikkene.
NILU
2025
Impact of leakage during HFC-125 production on the increase in HCFC-123 and HCFC-124 emissions
Hydrochlorofluorocarbons (HCFCs) are ozone-depleting substances whose production and consumption have been phased out under the Montreal Protocol in non-Article 5 (mainly developed) countries and are currently being phased out in the rest of the world. Here, we focus on two HCFCs, HCFC-123 and HCFC-124, whose emissions are not decreasing globally in line with their phase-out. We present the first measurement-derived estimates of global HCFC-123 emissions (1993–2023) and updated HCFC-124 emissions for 1978–2023. Around 5 Gg yr−1 of HCFC-123 and 3 Gg yr−1 of HCFC-124 were emitted in 2023. Both HCFC-123 and HCFC-124 are intermediates in the production of HFC-125, a non-ozone-depleting hydrofluorocarbon (HFC) that has replaced ozone-depleting substances in many applications. We show that it is possible that the observed global increase in HCFC-124 emissions could be entirely due to leakage from the production of HFC-125, provided that its leakage rate is around 1 % by mass of HFC-125 production. Global emissions of HCFC-123 have not decreased despite its phase-out for production under the Montreal Protocol, and its use in HFC-125 production may be a contributing factor to this. Emissions of HCFC-124 from western Europe, the USA and East Asia have either fallen or not increased since 2015 and together cannot explain the entire increase in the derived global emissions of HCFC-124. These findings add to the growing evidence that emissions of some ozone-depleting substances are increasing due to leakage and improper destruction during fluorochemical production.
2025
2025
Surveys in Norwegian schools showed that some students experienced health problems, such as headaches or concentration issues which have been linked to indoor environment quality (IEQ). This research investigates the relationship between measured IEQ and students’ perceived IEQ as user-feedback in one lower secondary school. This study explores the factors contributing to the connection with certain parameters such as carbon dioxide (CO2), volatile organic compounds (VOC), and temperature levels with perceived IEQ. Despite achieving good IEQ levels according to standards, there is a notable discrepancy between measured IEQ and how students perceive the air quality. Two classrooms served by a demand-controlled ventilation system were monitored with IEQ measurement sensors and online questionnaires were given individually to students in each classroom. This enables to provide real-time students’ perception of indoor air and room temperature quality. Measurement results showed IEQ are of good quality, but students’ responses on perceived IEQ vary and showed over 25% are dissatisfied, indicating mixed feelings and dissatisfaction about perceived IEQ. Future research should focus on refining ventilation systems to bridge the gap between measured and perceived IEQ.
2025
Supervised Anomaly Detection in Univariate Time-Series Using 1D Convolutional Siamese Networks
In time-series data analysis, identifying anomalies is crucial for maintaining data integrity and ensuring accurate analyses and decision-making. Anomalies can compromise data quality and operational efficiency. The complexity of time-series data, with its temporal dependencies and potential non-stationarity, makes anomaly detection challenging but essential. Our research introduces ADSiamNet, a 1D Convolutional Neural Network-based Siamese network model for anomaly detection and rectification. ADSiamNet effectively identifies localized patterns in time-series data and smooths detected anomalies using a quantile-based technique. In tests with physical activity data from Actigraph watches and MOX2-5 sensors, ADSiamNet achieved accuracies of 98.65% and 85.0%, respectively, outperforming other supervised anomaly detection methods. The model uses a contrastive loss function to compare input sequences and adjusts network weights iteratively during training to recognize intricate patterns. Additionally, we evaluated various univariate time-series forecasting algorithms on datasets with and without anomalies. Results show that anomaly-smoothed data reduces forecasting errors, highlighting our approach’s effectiveness in enhancing time-series data analysis’s integrity and reliability. Future research will focus on multivariate time-series datasets.
2025
Modelling Arctic lower-tropospheric ozone: processes controlling seasonal variations
Abstract. Previous assessments on modelling Arctic tropospheric ozone (O3) have shown that most atmospheric models continue to experience difficulties in simulating tropospheric O3 in the Arctic, particularly in capturing the seasonal variations at coastal sites, primarily attributed to the lack of representation of surface bromine chemistry in the Arctic. In this study, two independent chemical transport models (CTMs), DEHM (Danish Eulerian Hemispheric Model) and GEM-MACH (Global Environmental Multi-scale – Modelling Air quality and Chemistry), were used to simulate Arctic lower-tropospheric O3 for the year 2015 at considerably higher horizontal resolutions (25 and 15 km, respectively) than the large-scale models in the previous assessments. Both models include bromine chemistry but with different mechanistic representations of bromine sources from snow- and ice-covered polar regions: a blowing-snow bromine source mechanism in DEHM and a snowpack bromine source mechanism in GEM-MACH. Model results were compared with a suite of observations in the Arctic, including hourly observations from surface sites and mobile platforms (buoys and ships) and ozonesonde profiles, to evaluate models' ability to simulate Arctic lower-tropospheric O3, particularly in capturing the seasonal variations and the key processes controlling these variations. Both models are found to behave quite similarly outside the spring period and are able to capture the observed overall surface O3 seasonal cycle and synoptic-scale variabilities, as well as the O3 vertical profiles in the Arctic. GEM-MACH (with the snowpack bromine source mechanism) was able to simulate most of the observed springtime ozone depletion events (ODEs) at the coastal and buoy sites well, while DEHM (with the blowing-snow bromine source mechanism) simulated much fewer ODEs. The present study demonstrates that the springtime O3 depletion process plays a central role in driving the surface O3 seasonal cycle in central Arctic, and that the bromine-mediated ODEs, while occurring most notably within the lowest few hundred metres of air above the Arctic Ocean, can induce a 5 %–7 % of loss in the total pan-Arctic tropospheric O3 burden during springtime. The model simulations also showed an overall enhancement in the pan-Arctic O3 concentration due to northern boreal wildfire emissions in summer 2015; the enhancement is more significant at higher altitudes. Higher O3 excess ratios (ΔO3/ΔCO) found aloft compared to near the surface indicate greater photochemical O3 production efficiency at higher altitudes in fire-impacted air masses. The model simulations further indicated an enhancement in NOy in the Arctic due to wildfires; a large portion of NOy produced from the wildfire emissions is found in the form of PAN that is transported to the Arctic, particularly at higher altitudes, potentially contributing to O3 production there.
2025
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